N-(3-Methylbenzoyl)-2-nitrobenzenesulfonamide
نویسندگان
چکیده
In the title compound, C(14)H(12)N(2)O(5)S, the conformation between the N-H group and the ortho-nitro group in the sulfonyl benzene ring is syn and that between the C=O and meta-methyl groups in the benzoyl ring is anti. The mol-ecule is twisted at the S-N bond with a torsion angle of 64.3 (2)°. The dihedral angle between the sulfonyl benzene ring and the -SO(2)-NH-C-O segment is 75.73 (7)° and that between the sulfonyl and benzoyl benzene rings is 89.5 (1)°. The crystal structure features inversion-related dimers linked by pairs of N-H⋯O(S) hydrogen bonds.
منابع مشابه
N-(4-Methylbenzoyl)-4-nitrobenzenesulfonamide
In the title compound, C(14)H(12)N(2)O(5)S, the dihedral angle between the nitro-phenyl group and the -S-NH-C-O fragment is 80.74 (17)° and that between the nitro-phenyl and methyl-phenyl groups is 87.66 (14)°. The C-S-N-C torsion angle at the S-N bond is -67.0 (3)°. In the crystal, mol-ecules are linked into C(4) chains via N-H⋯O hydrogen bonds.
متن کاملN-(4-Methylbenzoyl)-2-nitrobenzenesulfonamide
The asymmetric unit of the title compound, C(14)H(12)N(2)O(5)S, contains two independent mol-ecules. The dihedral angles between the aromatic rings are 82.03 (9) and 79.47 (8)° in the two independent mol-ecules. In the crystal, the two mol-ecules in the asymmetric unit are linked into dimers via pairs of N-H⋯O(S) hydrogen bonds to generate C(4) chains.
متن کامل1-(4-Methylbenzoyl)-3-{2-[3-(4-methylbenzoyl)thioureido]phenyl}thiourea
In the title compound, C(24)H(22)N(4)O(2)S(2), the dihedral angles formed by the thio-ureido groups with the attached benzene ring are 43.81 (13) and 75.25 (13)°. The dihedral angle between the thio-ureido groups is 85.48 (10)°. The mol-ecule is stabilized by intra-molecular N-H⋯S, N-H⋯O and C-H⋯S hydrogen bonds. In the crystal, molecules are linked by intermolecular N-H⋯S hydrogen bonds togeth...
متن کاملN-(2-Chlorobenzoyl)-3-nitrobenzenesulfonamide
In the mol-ecule of the title compound, C(13)H(9)ClN(2)O(5)S, the dihedral angle between the two aromatic rings is 84.3 (1)°. In the crystal, mol-ecules are linked into chains via N-H⋯O(S) hydrogen bonds.
متن کاملN-(3-Chlorobenzoyl)-3-nitrobenzenesulfonamide
In the title compound, C(13)H(9)ClN(2)O(5)S, the dihedral angle between the two benzene rings is 83.5 (1)°. In the crystal, mol-ecules are linked via N-H⋯O(S) hydrogen bonds into helical chains running along the b axis.
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